期刊
CHEMICAL COMMUNICATIONS
卷 46, 期 34, 页码 6353-6355出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c0cc01406k
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-
资金
- NSFC [20841002, 20801002]
- U.S. Department of Energy, Division of Chemical Sciences, Office of Science [DE-FG02-09ER16000]
Selective oxidation of alcohol in water using molecular oxygen as the terminal oxidant is mediated by rhodium porphyrin complexes. Addition of methanol to an aqueous solution of (TSPP) Rh(III) resulted in observation of the key intermediate porphyrin rhodium(III) methoxide species. The activation parameters for beta C-H elimination of Rh-alkoxide were evaluated.
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