☆ 4.7 Article

Metal-dependent alternative activation of O-H and C-H bonds of methanol: on the formation and structure of bare [M,C,H-3,O](+) complexes (M = Fe, Co, Ni) in the gas phase

CHEMICAL COMMUNICATIONS (2010)

期刊

CHEMICAL COMMUNICATIONS

卷 46, 期 11, 页码 1878-1880

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ROYAL SOC CHEMISTRY

DOI: 10.1039/b924493j

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Chemistry, Multidisciplinary

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Structural aspects of the 'bare' [M(C,H-3,O)](+) complexes (M = Fe, Co, Ni), generated by electrospray ionization of aqueous methanolic solutions of MX2 (X = Br, I), have been probed in the gas phase by a combination of labeling studies and collision-induced dissociation (CID) experiments.

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