4.7 Article

Cerberus-type N-heterocyclic carbenes: synthesis and study of the first tritopic carbenes with D-3h-symmetry

期刊

CHEMICAL COMMUNICATIONS
卷 46, 期 28, 页码 5166-5168

出版社

ROYAL SOC CHEMISTRY
DOI: 10.1039/c0cc01070g

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资金

  1. National Science Foundation [CHE-0645563]
  2. Alfred P. Sloan Foundation [BR-4899]
  3. Robert A. Welch Foundation [F-1621]
  4. Division Of Chemistry [0741973] Funding Source: National Science Foundation

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The synthesis and characterization of tris(N-heterocyclic carbene)s with D-3h-symmetry is reported; these tritopic molecules feature three independent carbene moieties that are geometrically isolated to prevent chelation.

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