4.7 Article

Methylated molybdoplatinate-its unexpected ability to absorb methanol

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CHEMICAL COMMUNICATIONS
卷 46, 期 5, 页码 785-787

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ROYAL SOC CHEMISTRY
DOI: 10.1039/b915360h

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  1. MEXT of Japan [20036018]
  2. Photon Factory Program Advisory Committee [2007G639]

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Methylated molybdoplatinate of the Anderson structure was obtained as a tetra-n-butylammonium (TBA) salt by reacting MoO3, H2Pt(OH)(6), and aqueous TBAOH in a 6 : 1 : 4 ratio, which absorbed huge amounts of MeOH, more than three times as much as its own weight.

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