4.7 Article

Oxidative decarboxylation of alpha-hydroxy acids by a functional model of the nonheme iron oxygenase, CloR

期刊

CHEMICAL COMMUNICATIONS
卷 46, 期 11, 页码 1830-1832

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ROYAL SOC CHEMISTRY
DOI: 10.1039/b925389k

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资金

  1. U.S. National Institutes of Health [GM-33162]
  2. DST, India [SR/S1/IC-10/2006]
  3. NATIONAL INSTITUTE OF GENERAL MEDICAL SCIENCES [R01GM033162, R37GM033162] Funding Source: NIH RePORTER

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Iron(II)-alpha-hydroxy acid complexes of a tripodal N4 ligand undergo oxidative decarboxylation upon exposure to O-2 and mimic the aliphatic C1-C2 cleavage step catalyzed by CloR.

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