期刊
CHEMICAL COMMUNICATIONS
卷 46, 期 12, 页码 2133-2135出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/b926514g
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资金
- Fonds der Chemischen Industrie
- Alexander-von-Humboldt foundation
- German Research Foundation (DFG) [SFB 630]
Site-specific pK(a) determination of the carboxylate-binding subunit in artificial peptide receptors is achieved by pH-dependent UV resonance Raman scattering with subsequent matrix factorization. This quantitative methodology allows to determine accurately the local acidity of a binding site based on the complete vibrational spectrum and, most importantly, without the need of selecting any particular peak.
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