☆ 4.7 Article

Quantitative synthesis and full characterization of the first isolated and stable pincer palladium(IV) complexes. Quantitative and regioselective synthesis of the C-X ( X = Cl, Br) reductive elimination products

CHEMICAL COMMUNICATIONS (2010)

期刊

CHEMICAL COMMUNICATIONS

卷 46, 期 38, 页码 7253-7255

出版社

ROYAL SOC CHEMISTRY

DOI: 10.1039/c0cc02660c

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Chemistry, Multidisciplinary

资金

MICINN (Spain) [CTQ2007-60808/BQU]
Fundacion Seneca [04539/GERM/06 and 03059/PI/05]

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Reagent

摘要

The pincer complexes [Pd(O(1), N(1), C(1)-L) X], where X = Cl, Br and L is the monoanionic ligand resulting from deprotonation of the acetyl methyl group of the monoketal of 2,6-diacetylpyridine (dap), react with excess of Cl(2) or Br(2) affording, quantitatively, the Pd(IV) complexes [Pd(O(1), N(1), C(1)-L)X(3)], which have been characterized by X-ray diffraction, and their decomposition that quantitatively affords the reductive elimination products L-X has been studied.

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