期刊
CHEMICAL COMMUNICATIONS
卷 46, 期 16, 页码 2754-2756出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/b925402a
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资金
- National Natural Science Foundation of China [20773038, 20902023]
- Ministry of Science and Technology [2009CB724706, 2009ZX09501-016]
- China National Special Fund for State Key Laboratory of Bioreactor Engineering [2060204]
- Shanghai Leading Academic Discipline Project [B505]
A new chemo-enzymatic route to both isomers of 2-hydroxy-4-phenylbutyric acid is reported. The key step is the lactonase-catalyzed hydrolysis of cis- and trans-2-hydroxy-4-phenyl-4-butyrolactones followed by hydrogenation over Pd/C to afford optically pure 2-hydroxy-4-phenylbutyric acid.
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