期刊
CHEMICAL COMMUNICATIONS
卷 -, 期 19, 页码 2688-2690出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/b902729g
关键词
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资金
- Grants-in-Aid for Scientific Research [21390003] Funding Source: KAKEN
Density functional theory calculations demonstrate that Al(III)-catalyzed conversion of glyoxal to glycolic acid proceeds via a 7-membered dual Lewis acid-hydrogen bonding activation transition state of the 1,2-hydride shift, rather than the previously proposed 5-membered metal-alkoxide chelate activation transition state.
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