☆ 4.7 Article

Concise total synthesis of (+/-)-aspidospermidine via an oxidative Hosomi-Sakurai process

CHEMICAL COMMUNICATIONS (2009)

期刊

CHEMICAL COMMUNICATIONS

卷 -, 期 20, 页码 2941-2943

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ROYAL SOC CHEMISTRY

DOI: 10.1039/b903530c

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Chemistry, Multidisciplinary

资金

Donors of the Petroleum Research Fund
Natural Sciences and Engineering Research Council of Canada (NSERC)
provincial government of Quebec (FQRNT)

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摘要

A concise total synthesis of (+/-)-aspidospermidine has been achieved in twelve steps from inexpensive 4-ethylphenol, based on an oxidative Hosomi-Sakurai reaction via the concept of aromatic ring umpolung.

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