期刊
CHEMICAL COMMUNICATIONS
卷 -, 期 48, 页码 7587-7589出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/b918358b
关键词
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A mild and novel palladium(II)-catalyzed domino Heck/Suzuki alpha, beta-diarylation-reduction of a dimethylaminoethyl substituted chelating vinyl ether was developed by using electron-rich arylboronic acids in combination with p-benzoquinone. Based on the preparative results, a catalytic cycle is proposed. Further, highly regioselective palladium(II)-catalyzed alpha- or beta-monoarylation of the chelating vinyl ether was achieved using either a bidentate ligand or by employing ligand-less conditions.
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