4.7 Article

A four-shell, 136-metal 3d-4f heterometallic cluster approximating a rectangular parallelepiped

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CHEMICAL COMMUNICATIONS
卷 -, 期 29, 页码 4354-4356

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ROYAL SOC CHEMISTRY
DOI: 10.1039/b822609a

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  1. NSF CAREER [CHE-0238790]
  2. NNSFC [20531050, 20721001]
  3. MSTC [2007CB815304]

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A nanosized heterometallic cluster containing 60 La(III) and 76 Ni(II) ions, which are arranged into a four-shell, nest-like framework structure, was obtained by the hydrolytic reaction of the mixed La(NO3)(3)-Ni(NO3)(2) system using iminodiacetate as an ancillary ligand to control the hydrolysis.

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