期刊
CHEMICAL COMMUNICATIONS
卷 -, 期 35, 页码 4216-4218出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/b806492j
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资金
- Niigata University Research
The 1,4-elimination reaction of (Z)-N-Boc-2-(4-methoxy-2-alkenyloxy)pyrrolidines (1) is shown to proceed with high (1E, 3E)-stereoselectivity to afford N-Boc-2-(1,3-dienyloxy)pyrrolidines (2); the Bronsted acid catalyzed aza-Ferrier reaction of the N-Boc-2-(1,3-dienyloxy) pyrrolidines (2) provides alpha-(N-Boc-2- pyrrolidinyl) aldehydes (3) in excellent yields with high alpha-regioselectivities.
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