期刊
CHEMCATCHEM
卷 6, 期 11, 页码 3075-3079出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/cctc.201402560
关键词
carbon dioxide; copper; formate esters; hydrogenation; methanol
资金
- National Basic Research Program of China [2013CB933104]
- National Natural Science Foundation of China [21303246, 11275258]
The production of methanol, an important fuel and chemical feedstock, from carbon dioxide is an important process for CO2 utilization. We describe herein a mild and efficient method for the indirect hydrogenation of carbon dioxide to methanol via a CO2-derived formate ester intermediate by using a simple heterogeneous catalyst system comprising Cu highly dispersed in an alumina matrix under solvent-free conditions. This catalyst is also effective for the hydrogenation of other formate esters, such as ethyl formate, propyl formate, and butyl formate.
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