期刊
CHEMCATCHEM
卷 4, 期 2, 页码 243-250出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/cctc.201100321
关键词
aluminosilicates; heterogeneous catalysis; hydrogen bonds; immobilization; mesoporous materials; noncovalent interactions
资金
- Berzelii Center EXSELENT
- Swedish Research Council (VR) [2009-5237, 2007-4967, 2009-7551]
- Swedish Governmental Agency for Innovation Systems (VINNOVA)
- Faculty of Natural Sciences at Stockholm University
- Goran-Gustafsson Foundation
- VR
- Knut and Alice Wallenberg Foundation
The isomerization of allylic alcohols to carbonyl compounds by a heterogeneous rhodium complex is reported. Different silica material supports and catalyst/ligand systems were evaluated. The most efficient catalyst in terms of catalytic activity and stability was found to be a cationic rhodium(I) complex with sulfonated phosphine ligands anchored on a mesoporous aluminosilica AlSBA-15. The heterogeneous complex catalyzed the isomerization of a variety of allylic alcohols in excellent yields with very low catalyst loadings (0.5 mol?%). The catalyst could be recycled without significant loss of activity or selectivity. The optimized catalyst was characterized by N2 sorption, powder X-ray diffraction, transmission electron microscopy, as well as solution and solid-state nuclear magnetic resonance, and Fourier Transform infrared spectroscopies.
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