期刊
CHEMCATCHEM
卷 3, 期 9, 页码 1496-1502出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/cctc.201100076
关键词
ab initio calculations; amines; catalysis; hydrogenation; palladium
资金
- Australian Research Council
- Australian Government
The facile hydrogenolysis of various nitriles, imines, and amines over Pd/C has been achieved by using straightforward and relatively mild conditions. Substrates that contain an aryl group adjacent to the nitrogen-containing functionality were hydrogenolyzed most effectively. The stabilization of the proposed eta(2)-coordinated palladium intermediate by this group was partly responsible for this observation and is borne out by ab initio calculations.
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