4.7 Article

Influence of silicon sources on structures and properties of polyborosilazane precursor derived SiBNC ceramic fiber

期刊

CERAMICS INTERNATIONAL
卷 44, 期 17, 页码 21381-21385

出版社

ELSEVIER SCI LTD
DOI: 10.1016/j.ceramint.2018.08.194

关键词

SiBNC ceramic fibers; Cross-linking degree; Spinning behavior; Ceramic yield

资金

  1. Fundamental Research Funds for the Central Universities, China [2232018G-12]
  2. National Natural Science Foundation of China, China [51703025]
  3. Natural Science Foundation of Shanghai, China [15ZR1400400]

向作者/读者索取更多资源

Different kinds of polyborosilazane(PBSZ) precursors for SiBNC ceramic fibers were synthesized by SiCl4/HSiCl3/HSiMeCl2 with BCl3 and NH3CH3 via a one-pot method, respectively. FT-IR NMR, TG, and DSC were employed to study the influence of silicon sources(SiCl4/HSiCl3/HSiMeCl2) on chemical structures and physical properties of PBSZ precursors. FT-IR and NMR results indicated that these three kinds of PBSZs have similar chemical structures, which were mainly composed of Si-N bonds and B-N bonds in the backbone(linkage through-N(CH3)-bridges). The spinning behavior of the PBSZ precursors was also investigated. The results showed that PBSZ synthesized by HSiMeCl2 had the lowest glass-transition temperature and better melt spinnability. PBSZ synthesized by SiCl4 had the highest ceramic yield. Moreover, PBSZ synthesized by HSiCl3 was the most suitable candidate to produce SiBNC ceramic fibers, and the obtained SiBNC ceramic fibers exhibited good high-temperature stability which could keep its amorphous state at 1600 degrees C.

作者

我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。

评论

主要评分

4.7
评分不足

次要评分

新颖性
-
重要性
-
科学严谨性
-
评价这篇论文

推荐

暂无数据
暂无数据