4.7 Article

Synthesis of high alumina refractories from lithomargic clay

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CERAMICS INTERNATIONAL
卷 40, 期 4, 页码 6071-6075

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ELSEVIER SCI LTD
DOI: 10.1016/j.ceramint.2013.11.057

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Lithomargic clay; Gibbsite; Kaolinite; High alumina refractories

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Lithomargic clay underlying Awaso bauxite deposits consists mainly of kaolinite and minor fractions of gibbsite. Gibbsite, useful as a source of alumina, was separated from kaolinite. Gibbsite was added to lithomargic clay in various amounts, using Mfensi clay as a binder, and fired at 1350 degrees C for 2 h. Linear firing shrinkage, density, porosity, water absorption and cold crushing strength were used to characterize the fired bricks. The mineralogical compositions in the fired bricks were analyzed by X-ray diffraction techniques. The results showed that increasing the gibbsite amount up to 40 wt% increased the firing shrinkage and density whilst the apparent porosity and water absorption values decreased. Increasing the gibbsite amount enhanced mullite and corundum formation whilst the formation of free-silica phases was inhibited. The cold crushing strength increased linearly with increasing gibbsite content. (C) 2013 Elsevier Ltd and Techna Group S.r.l. All rights reserved.

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