期刊
CELLULOSE
卷 19, 期 6, 页码 2081-2091出版社
SPRINGER
DOI: 10.1007/s10570-012-9783-4
关键词
Fe3O4; Chitosan; Adsorption; Isotherm; Kinetics
资金
- 211 Project of Anhui University, Anhui Provincial Natural Science Foundation [1208085QB38]
- foundation for outstanding young talent in University of Anhui Province [2012SQRL024]
Fe3O4/chitosan/poly(acrylic acid) (Fe3O4/CS/PAA) composite particles, which are reusable, biodegradable and of high adsorption capacity, have been prepared through polymerizing acrylic acid in chitosan and Fe3O4 nanoparticles aqueous solution. By varying in-feed mole ratio of carboxyl to amino group (n(c)/n(a)) and reactant concentration, the average diameter of Fe3O4/CS/PAA composite particles can be controlled to vary from 100 to 300 nm. FT-IR, XRD and TEM were used to characterize Fe3O4/CS/PAA composite particles. Results showed that Fe3O4 was indeed incorporated into CS/PAA particles. The composite particles showed high efficient to remove copper ions (II) in aqueous solution. Adsorption kinetic studies showed that the adsorption process followed a pseudo-second-order kinetic model and the equilibrium data agreed well with the Langmuir model. The saturated adsorption capacity obtained from the experimental was 193 mg/g in close to proximity to the data 200 mg/g calculated from Langmuir model. The saturated adsorption capacity still retained 100 mg/g after three cycles of adsorption-desorption of copper ions (II).
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