期刊
CATALYSIS TODAY
卷 332, 期 -, 页码 35-41出版社
ELSEVIER
DOI: 10.1016/j.cattod.2018.08.018
关键词
Copper-amine complex; Cu-SAPO-44; Nitrogen oxides; Selective catalytic reduction; X-ray adsorption fine structure; Isolated Cu2+ ion
资金
- National Natural Science Foundation of China [21477046, 21876061]
- Key Technology R&D Program of Shandong Province [2016ZDJS11A03]
- State Key Laboratory of Chemical Engineering [CRE-2017-C-304]
A small-pore Cu-chabazite zeolite, Cu-SAPO-44 was synthesized using a one-pot approach by combination of cyclohexylamine template and copper-amine complex. The Cu-SAPO-44 zeolite obtained exhibits excellent activity over a wide temperature window from 200 to 500 degrees C for the selective catalytic reduction of NOx with ammonia (NH3-SCR). The copper-amine complex allowed direct introduction as well as a high dispersion of extra-framework Cu species in the chabazite structure. In situ X-ray absorption fine structure (XAFS) confirmed the isolated Cu2+ ions and Cu2+<-> Cu+ cycle. Temperature-programmed reduction with H-2 (H-2-TPR) and in situ FTIR of CO adsorption demonstrated that a variety of isolated Cu2+ ions inside the large cages and in or near the six-membered rings of the chabazite structure are responsible for the wide temperature window of activity. Cu-SAPO-44 has shown to be a promising candidate as a SCR catalyst with great potential in after-treatment systems for either mobile or stationary sources.
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