期刊
CATALYSIS TODAY
卷 130, 期 1, 页码 178-182出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.cattod.2007.08.015
关键词
benzene; adsorption; tungsten sulfides (WS(2)); hydrogenation (HYD); density-functional theory (DFT); pseudo-corner site; fourfold coordinated tungsten
Benzene adsorption on a model for a comer site of a WS(2) slab is considered by periodic DFT calculations. Under typical hydrotreating reaction conditions a fourfold coordination of the comer W atom is thought to be more favorable for benzene adsorption than five- or sixfold coordinated W atoms in conventional edge surfaces. Although no benzene adsorption site was identified on such a comer site, replacement of the W atom adjacent to the W comer site by Ni creates a potential adsorption site around the W corner site. Benzene was found to adsorb with Delta E = -0.19 eV on this Ni-substituted model for the comer site of a WS(2) slab. (C) 2007 Published by Elsevier B.V.
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