期刊
CATALYSIS LETTERS
卷 145, 期 2, 页码 505-510出版社
SPRINGER
DOI: 10.1007/s10562-014-1374-6
关键词
SILP catalysts; Hydrogenation; Ionic liquids; Membrane-like effect
资金
- FAPEMIG
- PRPq/UFMG
- CNPq
- CAPES
- PETROBRAS
In this work, the ionic liquid (IL) 1-hexyl-3-methyl-imidazolium bromide (HMIm.Br) containing Pd suspended nanoparticles was supported on a nanostructured magnetically recoverable carbon nanofiber network. The magnetic material was prepared by a simple reaction of ethanol directly with a nanostructured hematite. SEM, XRD, Mossbauer, Raman, TG/DTA, BET surface area and magnetization analyses suggested that the network is based on carbon nanofibers with carbon coated magnetic Fe nanoparticles. These magnetic networks offer a high exposed carbon fiber area, which has a good interaction with the IL to form a thin layer. Preliminary studies with a Pd dispersed in supported IL as catalyst for the hydrogenation of 1,5-cyclooctadiene showed a membrane effect, which leads to an important increase on the selective hydrogenation of 1,5-cyclooctadiene to cyclooctene.
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