期刊
CATALYSIS LETTERS
卷 144, 期 1, 页码 9-15出版社
SPRINGER
DOI: 10.1007/s10562-013-1142-z
关键词
Catalysis; Zeolites; Phenol; Hydroxylation; Redox; Pore size
资金
- University of Newcastle Australia
Reaction of phenol with hydrogen peroxide over H-MFI, Fe-MFI, H-BEA, Fe-BEA and TS-1 zeolite catalysts was investigated. Over H-BEA, biphenyl product was observed. It is suggested, that the larger pore size of H-BEA facilitates coupling of two phenol molecules. Two distinct reaction mechanisms are proposed for acid and redox catalysts.
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