期刊
CATALYSIS LETTERS
卷 142, 期 2, 页码 238-242出版社
SPRINGER
DOI: 10.1007/s10562-011-0751-7
关键词
Isomerization-hydroformylation; Homogeneous catalysis; 2-Butene; Rhodium complex
资金
- National Natural Science Foundation of China [21072138]
The formation of linear aldehyde from isomerization-hydroformylation of 2-butene represents an important subject and current task in industry. Both high activity and excellent regioselectivity were achieved in the rhodium-catalyzed 2-butene isomerization-hydroformylation with 2,2'-bis(dipyrrolylphosphinooxy)-1,1'-(+/-)-binaphthyl (1) as ligand. Bulky phosphite with electron-withdrawing pyrrol groups dramatically improved the selectivity of linear product, and a good yield of 90.5% aldehydes was obtained with an excellent linear aldehyde regioselectivity of 95.3% under optimized condition.
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