4.5 Article

1, 4-Addition of Terminal Alkynes to Conjugated Enones in Water Using Green Catalyst Bis[(L)prolinato-N,O]Zn-An Environmentally Benign Protocol

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CATALYSIS LETTERS
卷 141, 期 1, 页码 183-190

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SPRINGER
DOI: 10.1007/s10562-010-0451-8

关键词

Bis[(L)prolinato-N,O]Zn; gamma, delta-Acetylenic ketones; 1,4-Addition; Water as a solvent; Recyclability; TEM; Powder XRD

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  1. UGC
  2. CSIR, New Delhi

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An easy, low cost, and green procedure is proposed for the 1, 4-addition of terminal alkynes to conjugated enones in water as a sole medium using easily accessible Zn[(L)Proline](2). This protocol has advantages of high yield, mild reaction conditions, no environmental pollution and simple work up procedure.

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