期刊
CATALYSIS LETTERS
卷 139, 期 1-2, 页码 56-60出版社
SPRINGER
DOI: 10.1007/s10562-010-0385-1
关键词
Cyanation; Palladium; Aryl chlorides; Benzonitriles; Potassium ferrocyanide; Water
资金
- National Natural Science of Foundation of China [20802008]
- Foundation from State Key Laboratory of Materials-Oriented Chemical Engineering, Nanjing University of Technology
A highly improved Pd-catalyzed cyanation of aryl chlorides to corresponding benzonitriles was demonstrated in aqueous media. Moreover, Pd-catalyzed cyanation of aryl tosylates and benzenesulfonates with K(4)[Fe(CN)(6)] was developed under the similar conditions, which extended application scope of the cyanation.
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