期刊
CATALYSIS COMMUNICATIONS
卷 37, 期 -, 页码 60-63出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.catcom.2013.03.031
关键词
Diphenylmethane; Benzophenone; Oxidation; Ruthenium; tert-Butylhydroperoxide
资金
- National Natural Science Foundation of China [21036009, 21176267]
- Natural Science Foundation of Guangdong Province [10152404801000017]
The ruthenium complex Ru(bpbp)(pydic) (bpbp = 2,6-bis(1-phenylbenzimidazol-2-yl), pydic = pyridine-2,6-dicarboxy acid) has been synthesized and tested in the selective oxidation of diphenylmethane to benzophenone utilizing tert-butylhydroperoxide as the terminal oxidant. The influence of various reaction parameters such as temperature, catalyst amount and nature of solvent on the activity and selectivity was evaluated. Diphenylmethane was converted with 94% conversion and 100% selectivity to benzophenone under the optimized reaction conditions, in which the turnover number (TON) of catalyst reached 94,000. Moreover, a plausible reaction mechanism through redox ruthenium species was proposed. (C) 2013 Elsevier B.V. All rights reserved.
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