期刊
CATALYSIS COMMUNICATIONS
卷 12, 期 6, 页码 489-492出版社
ELSEVIER
DOI: 10.1016/j.catcom.2010.11.013
关键词
Iron(II) complexes; Cyclotrimerization of alkynes; Tridenate nitrogen ligand; Alkynes
资金
- National Natural Science Foundation of China [20872076, 20972085, 21032004]
- Specialized Research Fund for the Doctoral Program of Higher Education [200800030072]
FeCl2 ligated with 2-(benzimidazolyl)-6-(1-(arylimino)ethyl)pyridine in the presence of zinc powder and zinc iodide could effectively catalyze cyclotrimerization of intermolecular alkynes to afford benzene derivatives in high regioselectivity. The synthetic usefulness of this catalytic system consisting of Fe(II) complex C1, Zn and Znl(2) in acetonitrile was tested with various terminal alkynes. In the cases of using aryl substituted alkynes, the 1,2,4-trisubstituted benzenes 2 were found to be the major products. (C) 2010 Elsevier B.V. All rights reserved.
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