期刊
CARBON
卷 46, 期 7, 页码 1010-1016出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.carbon.2008.02.029
关键词
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Fluorination of carbon nanofibres (CNFs) under fluorine gas at 480 degrees C leads to high fluorine content but also to some partial exfoliation. In order to avoid such phenomenon, an alternative route has been performed at temperatures ranged between 420 and 500 degrees C using a fluorinating agent, i.e. terbium tetrafluoride. The structural properties of the fluorinated CNFs are discussed taking into account the data of C-13 solid state NMR, Raman spectroscopy, SEM, TEM and XRD. Whatever the fluorination temperature, a fluorinated phase of (CF)(n) structural type, is formed contrary to the direct process using F-2 gas for which a (C2F)(n)-type fluorinated phase appeared for fluorination temperatures lower than 450 degrees C. The progressive release of fluorine atoms from the thermal decomposition of TbF4 allows an homogenous distribution of the fluorinated part into the CNFs matrix and the formation of a unique (CF)(n) type structure. Moreover, for high fluorination temperatures (480 and 500 degrees C), the fluorination leads to some nanofibres breaking but in no way to exfoliation. (c) 2008 Elsevier Ltd. All rights reserved.
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