期刊
CARBOHYDRATE RESEARCH
卷 346, 期 7, 页码 986-990出版社
ELSEVIER SCI LTD
DOI: 10.1016/j.carres.2011.03.003
关键词
Crystal structure; Powder X-ray diffraction; beta-Cyclodextrin; p-Aminobenzoic acid; Inclusion complex
The 1:1 inclusion complex of beta-cyclodextrin and p-aminobenzoic acid was prepared and characterized by TG-DTA. The crystal structure of the complex was solved directly from powder X-ray diffraction data using the direct space approach and refined using Rietveld refinement techniques. The complex crystallizes in monoclinic P2(1) space group, with unit cell parameters a = 20.7890 angstrom, b = 10.2084 angstrom, c = 15.1091 angstrom. beta = 110.825 degrees, V = 2997 angstrom(3). The amino group is located at the wide side of the beta-cyclodextrin cavity, forming hydrogen bonds with beta-cyclodextrin, and the carboxyl group is located at the narrow side. The crystallographic data obtained from powder diffraction data were compared with the single crystallographic data, and the result shows that solving crystal structure of cyclodextrins inclusion complexes of such complexity is accessible to powder diffractionists to some extent. (C) 2011 Elsevier Ltd. All rights reserved.
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