期刊
CARBOHYDRATE POLYMERS
卷 101, 期 -, 页码 705-713出版社
ELSEVIER SCI LTD
DOI: 10.1016/j.carbpol.2013.09.089
关键词
Agaran; Red seaweed polysaccharide; Sulfated polysaccharide; Galactan structure; Laurencia
资金
- National Research Council of Argentina [112-200801-00234]
- University of Buenos Aires [X137/2008-2010, 20020100100479/2011-2014]
- FONACIT [2012000830]
The water extracts from red seaweeds Laurencia obtusa and Laurencia filiformis comprise complex sulfated agarans. Those from L. obtuse have 3-linked beta-D-galactose units in part sulfated on 2-position or methylated on 6-position, while the 4-linked units are mostly 3,6-anhydro-alpha-L-galactose and a-L-galactose 6-sulfate, some of the latter units are substituted with beta-D-xylose on 3-position, precluding alkaline cyclization. The 3-linked beta-D-galactose units of the agarans from L filiformis are mostly sulfated on 2-position, but approximately half of these residues also carry the 4,6-0-(1-carboxyethylidene) group. The 4-linked 3,6-anhydro-alpha-L-galactose units are methylated or substituted in part with single stubs of beta-D-xylose on 2-position. This is the first time that substitution with xylose of 3,6-anhydro-alpha-L-galactose is reported. Besides, alpha-L-galactose 2-sulfate carrying single stubs of beta-D-xylose on 3-position was also detected. These galactans have some common structural characteristics with those of other species of this genus, but also others that are specific for these species. (C) 2013 Elsevier Ltd. All rights reserved.
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