期刊
CARBOHYDRATE POLYMERS
卷 99, 期 -, 页码 356-364出版社
ELSEVIER SCI LTD
DOI: 10.1016/j.carbpol.2013.08.075
关键词
Xylan; Films; Composites; Mechanical testing; Thermal properties
资金
- Slovak Granting Agency VEGA [2/7030/7, 2/0087/11, 2/0007/13]
- [2003SP200280203]
- [20035P200280301]
Xylan quaternized sulfate films were prepared from beech xylan (X) and compared with fully sulfated xylan films (XS). When quaternized xylan (QX) was prepared in the first step (DSQ = 0.55), than by sulfation of QX in the second step the fully substituted ampholytic derivative (QXS; DSQ = 0.33; DSs =1.67) could be obtained. By sulfation in first step, xylan sulphate (SX, DSs = 0.70) was obtained and by subsequent quaternization, SXQ film with DSQ = 0.55 and DSs = 0.33 which contained partially unsubstituted hydroxyls. The molar masses (M) of the film's soluble parts were increasing in order X < SX < SXQ < QX < XS < QXS. In all films there were some insoluble particles present as determined by the amount of recovered masses by SEC-MALS. The materials were further characterized by AFM, XRD,TG/DTG/DTA, NMR and mechanical testing. QXS and SXQ could form mechanically more stable films than XS specimens. (C) 2013 Elsevier Ltd. All rights reserved.
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