Article
Environmental Sciences
Jin Zhang, Kun Wang, Qitao Yi, Tao Zhang, Wenqing Shi, Xuefei Zhou
Summary: This study reveals that metal transport and partitioning in plain river networks with sedimentary resuspension are primarily controlled by suspended solids and seasonal flow regimes. The concentration of metals is associated with suspended solids in the water column and decreases from low flow to high flow, while the partitioning between particulate phase and dissolvable phases is reversed and increases from low flow to high flow. The findings provide insights into the ecological risks posed by metals in downstream lakes and highlight areas with heavy metal pollution and the transport routines of metals in river networks.
ENVIRONMENTAL POLLUTION
(2022)
Article
Multidisciplinary Sciences
Laura Navarro, Ricardo Camacho, Julian E. Lopez, Juan F. Saldarriaga
Summary: This study aims to obtain leaching risk maps of pesticides under an onion crop in Tibasosa, Boyacá, Colombia by studying soil types, analyzing pollutant behavior, and utilizing GIS technology for visualizing areas of greater potential risk.
Article
Environmental Sciences
Jun Hu, Zhen Wang, Gordon D. Z. Williams, Gary S. Dwyer, Luke Gatiboni, Owen W. Duckworth, Avner Vengosh
Summary: This study investigates the accumulation of metal(loid)s originating from phosphate fertilizer in agricultural soils and plants, suggesting that the excessive application of phosphate fertilizers can lead to the accumulation of toxic metal(loid)s, increasing human exposure risks.
SCIENCE OF THE TOTAL ENVIRONMENT
(2024)
Article
Environmental Sciences
Yun Deng, Wang Xu, Qinghuai Zeng, Feiyun Sun, Fei Wang, Yanjie Li
Summary: The soil-air partition coefficients (KSA) of PBDEs and OPFRs were measured using a solid-phase fugacity meter, and the effects of temperature and relative humidity on KSA values were analyzed. An inverse relationship was found between temperature/RH and KSA values for both PBDEs and OPFRs. The study also found a significant correlation between log KSA and log KOA. The experimental KSA values differed greatly from the predicted values based on KOA. This study provides a better understanding of the behavior and fate of PBDEs and OPFRs in soil-air systems.
Review
Metallurgy & Metallurgical Engineering
Huan Li, Zixian Deng, Elsayed Oraby, Jacques Eksteen
Summary: In the past decade, there has been significant interest in non-conventional lixiviants, particularly organic acids and amino acids. Among the amino acids, glycine is widely studied as a non-toxic, non-volatile, and recyclable reagent for leaching base and precious metals. The glycine leaching system shows promise as an alternative to traditional methods in the hydrometallurgical industry.
Article
Chemistry, Medicinal
Cayque Monteiro Castro Nascimento, Andre Silva Pimentel
Summary: Large language models (LLMs) have the potential to revolutionize complex question answering using the ChatGPT model, but its application in chemistry is still in its early stages. This viewpoint presents five simple tasks in different areas of chemistry to assess how well ChatGPT understands the subject.
JOURNAL OF CHEMICAL INFORMATION AND MODELING
(2023)
Article
Spectroscopy
Andrzej Czyrski
Summary: This study investigated the apparent partition coefficients of two amphoteric drugs, levofloxacin and ciprofloxacin, and found that both drugs were lipophilic. The neutral forms dominated in the conditions relevant to intestinal absorption.
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY
(2022)
Article
Biotechnology & Applied Microbiology
Ankit, Lala Saha, Virendra Kumar, Jaya Tiwari, Sweta, Shalu Rawat, Jiwan Singh, Kuldeep Bauddh
Summary: Electronic waste is a significant part of solid waste management worldwide, containing hazardous components that have adverse effects on plants, microbes, and human beings. Heavy metals are a major toxic component of e-waste, requiring careful handling. Inadequate disposal/treatment technologies for e-waste have direct and indirect impacts on human health and the environment.
ENVIRONMENTAL TECHNOLOGY & INNOVATION
(2021)
Article
Environmental Sciences
Guangjun Peng, Pengpeng Zhang, Linghao Zeng, Lin Yu, Dongwei Li
Summary: This study investigated the leaching characteristics of heavy metals in three simulated environments after immobilizing Chromium ore processing residue (COPR) with composite binders. The results showed that heavy metals were mainly released from the solidified body through surface washing at a low rate. Chemical binding and physical encapsulation were the main immobilizing mechanisms to achieve coordinated disposal of Zn and Cr(VI).
ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH
(2023)
Article
Environmental Sciences
Sapna Kumari Pandey, Kunal Roy
Summary: ETA indices can be used for developing QSPR models for logK(ow) and logK(oc), with molecular volume, branching pattern, environmental characteristics, and chemical structure playing crucial roles in determining the properties of compounds.
ECOTOXICOLOGY AND ENVIRONMENTAL SAFETY
(2021)
Article
Engineering, Chemical
Binxin Huang, Yu Tong, Yong Chen, Ali Eslamimanesh, Weifeng Shen, Shun'an Wei
Summary: This study combines genetic algorithm with random forest algorithm to select suitable molecular feature combination, significantly reducing the number of descriptors required for model development, and utilizes a combination of backpropagation neural network and Bayesian optimization for intelligent tuning of relevant model parameters.
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH
(2022)
Article
Chemistry, Multidisciplinary
Pierre Trinh, Alesya Mikhailovskaya, Mengxue Zhang, Patrick Perrin, Nadege Pantoustier, Gregory Lefevre, Cecile Monteux
Summary: The study focuses on using aqueous leaching foams for efficient oxidation and dissolution of metals in electronic waste, extending the concept to ozone for oxidizing other metals, and improving metal dissolution by using anionic surfactants. These promising results offer new recycling routes for metals in electronic waste, with a lower environmental footprint.
ACS SUSTAINABLE CHEMISTRY & ENGINEERING
(2021)
Article
Geochemistry & Geophysics
Angel Jimenez-Arroyo, Rinat Gabitov, Artas Migdisov, Juejing Lui, Andrew Strzelecki, Xiaodong Zhao, Xiaofeng Guo, Varun Paul, Todd Mlsna, Alberto Perez-Huerta, Florie Caporuscio, Hongwu Xu, Robert Roback
Summary: The goal of this work was to evaluate the immobilization of uranium through crystallization of calcium phosphate minerals. The experiments showed that phosphates, especially apatite, has a strong potential to immobilize uranium under hydrothermal conditions and can be used in the development of engineering barriers in nuclear waste disposal.
Article
Chemistry, Medicinal
Iraide Saez-Zamacona, Guillermo Grindlay, Rosa Maria Martinez-Espinosa
Summary: This study aimed to assess the Cd(II) bioremediation potential of Hfx. mediterranei R4. It was found that the cell doubling time of Hfx. mediterranei increased three times in the presence of Cd(II) in the culture medium. Moreover, the microorganism was able to accumulate Cd, with the highest accumulation observed at a concentration of 0.4 mM. Additionally, the presence of Cd(II) affected the levels of other elements in the biomass, increasing the levels of K and Mn while reducing the levels of Mg and Zn.
Article
Environmental Sciences
Mary A. Gilliam, Dan van Cura, Graham Garner, Allison Seeley, Ryan Sekol
Summary: This study establishes empirical relationships for estimating the diffusion and solid/air partition coefficients of phthalates in PVC materials. A test chamber and SPME method were used to validate the model, which can be applied to outdoor and manufacturing scenarios.