期刊
CANADIAN JOURNAL OF CHEMISTRY
卷 86, 期 3, 页码 225-229出版社
CANADIAN SCIENCE PUBLISHING
DOI: 10.1139/V08-010
关键词
carbanions; 4-nitrobenzofurazan; sigma-adducts; elimination reactions
H-1 NMR studies in [H-2(6)]-DMSO show that the carbanion 4 from bis(phenylsulfonyl)methane reacts with 4,6-dinitrobenzofuroxan to yield a sigma-adduct that undergoes base-catalysed elimination to yield an alkene derivative. Rate constants, measured spectrophotometrically, are reported for the corresponding reactions in methanol of 4 with 4-nitrobenzofurazan and some derivatives that give adducts at the 5-position. The intrinsic rate constant, k(o), for this process has a value of 1.5 +/- 0.5. The 5-adducts undergo methoxide-catalysed elimination of phenylsulfinic acid to yield alkene derivatives and rate constants for this process are reported.
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