期刊
BULLETIN OF THE KOREAN CHEMICAL SOCIETY
卷 33, 期 7, 页码 2251-2254出版社
WILEY-V C H VERLAG GMBH
DOI: 10.5012/bkcs.2012.33.7.2251
关键词
N-Formylation; Amines; Solvent-free; Natural HEU zeolite; Formic acid
资金
- Ahar Branch, Islamic Azad University
A rapid and practical green route for N-formylation of primary and secondary amines with formic acid at room temperature under the solvent-free conditions using HEU zeolite as a heterogeneous, reusable and highly efficient catalyst is described. The process is remarkably simple and environmentally benign. Excellent chemoselectivity was observed for the conversion of primary amines in the presence of secondary amines.
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