4.2 Article Proceedings Paper

ZnO 1-D nanostructures: Low temperature synthesis and characterizations

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BULLETIN OF MATERIALS SCIENCE
卷 31, 期 3, 页码 551-559

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INDIAN ACAD SCIENCES
DOI: 10.1007/s12034-008-0086-1

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aligned 1-D ZnO nanostructures; surfactant mediated growth; optical absorption and emission; field emission properties

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ZnO is one of the most important semiconductors having a wide variety of applications in photonic, field emission and sensing devices. In addition, it exhibits a wide variety of morphologies in the nano regime that can be grown by tuning the growth habit of the ZnO crystal. Among various nanostructures, oriented 1-D nanoforms are particularly important for applications such as UV laser, sensors, UV LED, field emission displays, piezoelectric nanogenerator etc. We have developed a soft chemical approach to fabricate well-aligned arrays of various 1-D nanoforms like nanonails, nanowires and nanorods. The microstructural and photoluminescence properties of all the structures were investigated and tuned by varying the synthesis parameters. Field emission study from the aligned nanorod arrays exhibited high current density and a low turn-on field. These arrays also exhibited very strong UV emission and week defect emission. These structures can be utilized to fabricate efficient UV LEDs.

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