4.4 Article

Metal Oxide Nanomaterials for the Photodegradation of Phenol

期刊

ANALYTICAL LETTERS
卷 49, 期 6, 页码 855-866

出版社

TAYLOR & FRANCIS INC
DOI: 10.1080/00032719.2015.1079211

关键词

Adsorption; metal oxide nanomaterials; phenol; photocatalytic degradation

资金

  1. Education Department of Gansu Province [2014B-111]

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The decomposition of phenol by four metal oxide nanomaterials was investigated by adsorption and photocatalytic degradation. The results from adsorption experiments were fit to a Langmuir model. The theoretical monolayer adsorption capacities for nano-TiO2, -Al2O3, -ZnO, and -CuO were approximately 14.35, 14.28, 13.72, and 5.29mg/g, respectively. Nano-TiO2 and -CuO had the largest Langmuir model coefficients: both were 0.0324L/mg. The adsorption capacity of phenol was higher in basic conditions than in acidic solution. Photodegradation was characterized by pseudo-first-order models. The total removal rates for nano-TiO2, -Al2O3, -ZnO, and -CuO after 3 hours of irradiation were 89.0%, 70.8%, 57.3%, and 61.6%, respectively. The differences between phenol and total organic carbon concentrations for nano-TiO2, -Al2O3, -ZnO, and -CuO were 42.92%, 20.11%, 8.29%, and 16.78%, respectively. Nano-TiO2 provided the maximum capacity for photodegradation and produced the most intermediates. The majority of the phenol was degraded to resorcinol and hydroquinone as intermediates to acetic acid.

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