Article
Chemistry, Analytical
Mengmeng Zhang, Xiaoyang Wang, Yajun Zhang, Yiqiang Fan
Summary: This study proposes an integrated microfluidic approach for the quantification of microplastics from river water sediment and biosamples. The proposed two-layer PMMA-based microfluidic device is capable of conducting the sample digestion, filtration, and counting processes inside the microfluidic chip with preprogrammed sequence. The results from the analysis of samples from river water sediment and fish gastrointestinal tract demonstrate that the proposed microfluidic device can perform the quantification of microplastics from river water and biosamples.
ANALYTICA CHIMICA ACTA
(2023)
Article
Chemistry, Physical
Y. Q. Huang, N. Kang
Summary: Interfacing graphene with other low-dimensional materials has attracted attention recently due to its potential for new physics and device innovations. In this study, colloidal quantum dots (CQDs) were introduced to a bilayer graphene device using a solution-processed approach. The presence of the CQDs drastically altered the magnetotransport properties of the graphene device, leading to the observation of AB-like oscillation in the quantum Hall regime and screening of intervalley scattering. This study demonstrates the potential of this flexible method for engineering microscopic scattering processes and improving the performance of graphene devices.
JOURNAL OF COLLOID AND INTERFACE SCIENCE
(2024)
Article
Engineering, Electrical & Electronic
O. Zaca-Moran, J. F. Sanchez-Ramirez, J. L. Herrera-Perez, J. Diaz-Reyes
Summary: Graphene oxide quantum dots were synthesized from electrospun PAN nanofibers through carbonization, ultrasonic exfoliation, and oxidation processes. The resulting GOQDs showed a high density of crystalline defects and emitted radiative bands in the blue spectral region.
MATERIALS SCIENCE IN SEMICONDUCTOR PROCESSING
(2021)
Article
Engineering, Electrical & Electronic
Weijia Cui, Zahra Abbasi, Carolyn Ren
Summary: Lead contamination in drinking water poses serious health risks, especially for children. This study presents an inexpensive and portable detection system for monitoring lead concentration in drinking water. The system utilizes a microchannel and a microwave resonator-based sensor integrated with a microfluidic chip. Experimental results demonstrate the high sensitivity of the system and its potential for on-site monitoring of lead contamination.
SENSORS AND ACTUATORS A-PHYSICAL
(2023)
Article
Chemistry, Analytical
Hui-Min Zhai, Bin Ji, Shan-Shan Tian, Fang Fang, Shuang Zhao, Zhi-Yong Wu
Summary: This study introduces a new method for Cr speciation analysis based on a paper-based analytical device (PAD), which uses electrokinetic separation and stacking to separate and recover Cr (VI) and Cr (III) with high sensitivity and recovery rates. This fast, cheap, and easy-to-use sample pretreatment method can be applied for direct analysis of Cr (VI)/Cr (III) in electroplating wastewater samples.
Article
Chemistry, Analytical
Zengming Zhang, Shuhao Zhao, Lei Jiang, Junjun Wu, Wenhan Zhao, Xiaoniu Guo, Niancai Peng, Fei Hu
Summary: By optimizing a microfluidic system, we have successfully developed a simple, rapid, and cost-effective DNA quantification method. The method enables efficient DNA extraction and PCR amplification through the gradient thermal effect. The application of this microfluidic technology holds great promise in decentralized laboratories and low-resource settings.
Article
Engineering, Electrical & Electronic
Mrunali D. Wagh, Subhendu Kumar Sahoo, Sanket Goel
Summary: The research introduces a microfluidic device with integrated microchannel and interdigitated electrodes based on capacitive sensing mechanism manufactured using the laser-induced graphene technique. The device demonstrated linear impedance change for different chemicals in the range of 1-1000 ppm under microfluidic conditions, with a minimum detection limit of 1 ppm. The microfluidic taste sensor has the potential to provide low-cost, simple-to-integrate multi-functional point-of-care sensors for human sensory tastes, clinical, and environmental applications.
SENSORS AND ACTUATORS A-PHYSICAL
(2022)
Article
Chemistry, Multidisciplinary
Hoang Khang Bui, Vu Minh Phan, Huynh Quoc Nguyen, Van Dan Nguyen, Hiep Van Nguyen, Tae Seok Seo
Summary: We proposed a portable sample pretreatment microsystem that can be operated automatically through speech recognition in a smartphone app. The microsystem includes a microfluidic chip, an air router, pressure and vacuum lines with air pump motors, six 3-way solenoid valves, and a microcontroller with a Bluetooth module. The entire DNA extraction process from pathogenic bacterial samples is controlled by human voice commands, eliminating manual interference and potential infection. The palm-sized microsystem can be powered by a portable battery or a conventional smartphone charger, achieving a DNA extraction efficiency of 70 +/- 5% for Salmonella typhimurium in less than 1 minute.
Article
Chemistry, Analytical
Parisa Gouran Oorimi, Aliakbar Tarlani, Reza Zadmard, Jacques Muzart
Summary: This report presents a simple and highly sensitive photoluminescence sensor for detecting fatal cyanide ions using a novel composite material made from graphene quantum dots (GQDs) encapsulated in zeolitic imidazolate framework (ZIF-11). The sensor demonstrated excellent detection capabilities with a wide linear range, low relative standard deviation, and a very low limit of detection. It also showed good sensitivity towards cyanide ions in the presence of other interfering ions. Real cyanide samples from apple seeds and bitter almonds were successfully detected using this sensor. The reliable and valuable performance of this sensor makes it a promising candidate for cyanide ion detection.
MICROCHEMICAL JOURNAL
(2023)
Article
Chemistry, Multidisciplinary
Jin Song, Ashaq Ali, Yaohong Ma, Yiwei Li
Summary: In this study, a microfluidic system using a graphene-modified microelectrode array sensor was proposed for real-time monitoring of bacterial biofilms through electrochemical impedance. The results showed that increasing bacterial cell load on the sensing interface significantly prolonged the observation window period of the biofilm state, thereby improving the sensing signal quality. Simulation studies demonstrated that this method outperformed traditional endpoint detection in anti-biofilm drug screening.
NANOSCALE ADVANCES
(2023)
Article
Biochemical Research Methods
Benjamin P. Sullivan, Andrew T. Bender, Duy N. Ngyuen, Jane Yuqian Zhang, Jonathan D. Posner
Summary: The translation introduces a paper-based device that uses isotachophoresis to extract and purify nucleic acids from whole blood, providing a simpler sample preparation method for point-of-care NAATs.
JOURNAL OF CHROMATOGRAPHY B-ANALYTICAL TECHNOLOGIES IN THE BIOMEDICAL AND LIFE SCIENCES
(2021)
Article
Biophysics
Wan Wang, Shounian Ding, Zhijuan Wang, Qing Lv, Qing Zhang
Summary: In this study, a microfluidic paper-based analytical device (muPAD) was developed for the online isolation of proteins and electrochemical detection of lead ions (Pb(II)) in urine samples. Experimental parameters were optimized, leading to a maximum protein concentration of 300 mg L-1, a linear range of 10-500 µg L-1, and a detection limit of 9 µg L-1. The device's effectiveness was demonstrated through quantification of Pb(II) in urine samples, showing results consistent with atomic absorption spectrometry (AAS).
BIOSENSORS & BIOELECTRONICS
(2021)
Review
Chemistry, Analytical
Ping Yang, Gangrong Fu, Jiang Wang, Ziyi Luo, Mingyin Yao
Summary: This article reviews the applications of LIBS in the analysis of agricultural products and explores its capabilities in qualitative and quantitative analysis of different samples. The authors also discuss the potential of LIBS for real-time elemental analysis of agricultural products and practical applications in precision farming.
JOURNAL OF ANALYTICAL ATOMIC SPECTROMETRY
(2022)
Article
Engineering, Environmental
Yu-Qiong Liu, Xiao-Jie Ju, Xing-Qun Pu, Shuang Wen, Wen-Ying Liu, Zhuang Liu, Wei Wang, Rui Xie, Liang-Yin Chu
Summary: A simple and portable thermometer-type device utilizing forward osmosis-driven liquid column rising has been developed for visual detection of trace Pb2+. This device is capable of detecting trace Pb2+ concentrations as low as 10(-10) M in aqueous solutions, providing a novel and simple strategy for visual detection of trace Pb2+.
JOURNAL OF HAZARDOUS MATERIALS
(2021)
Article
Chemistry, Analytical
Naresh Mandal, Victor Pakira, Nirmalya Samanta, Naren Das, Suman Chakraborty, Bidhan Pramanick, Chirasree RoyChaudhuri
Summary: The study introduces an affordable label free graphene FET sensor for PSA detection, integrated with a microfluidic platform, achieving high selectivity and sensitivity.
Article
Chemistry, Multidisciplinary
Hyeong Jun Lee, Sanghyuk Park, Jong Bin Kim, Shin-Hyun Kim
Summary: Colloidal lithography is used to create regular micro- and nano-patterns by employing colloidal crystals as masks. By utilizing the capillary wetting effect and photoresists, 3D structures with undulated surfaces can be designed.
ADVANCED FUNCTIONAL MATERIALS
(2023)
Article
Biochemical Research Methods
Yong Tae Kim, Alireza Ahmadianyazdi, Albert Folch
Summary: Methods using 3D printers to make microfluidic chips have gained much attention for their simple procedures and minimal human intervention. Challenges lie in printing high-resolution chips that are transparent, biocompatible, and contain regions of dissimilar materials. The 'print-pause-print' protocol demonstrates strategies for fabricating transparent biomicrofluidic devices and multimaterial chips. The procedure takes less than 1 hour and enables various chip-based applications.
Article
Chemistry, Multidisciplinary
Sehee Yang, Young Geon Kim, Sanghyuk Park, Shin-Hyun Kim
Summary: Researchers have developed photonic microcapsules with dual or triple stopbands, offering a wider range of colors and optical codes. By manipulating interparticle interactions, they were able to control the size and composition of crystalline grains in the microcapsules, resulting in controllable mixed structural colors and reflectance spectra.
ADVANCED MATERIALS
(2023)
Article
Chemistry, Physical
Ji-Won Kim, Sang Hoon Han, Minhee Ku, Jaemoon Yang, Shin-Hyun Kim
Summary: Chemophotothermal therapy is a promising cancer treatment method that combines photothermal agents and drugs. However, low payload, burst release, and dilution have limited its effectiveness. To overcome these limitations, smart microcapsules were designed as a practical material for chemophotothermal therapy. Water-in-oil-in-water double-emulsion templates were produced to encapsulate photothermal nanoparticles and drugs. The microcapsules release drugs when the phase-change material (PCM) in the polymer shell melts, while retaining drugs without leakage when frozen. The concentrated nanoparticles provide rapid and intense heating, allowing for controlled drug release using near-infrared irradiation.
CHEMISTRY OF MATERIALS
(2023)
Correction
Biochemical Research Methods
Yong Tae Kim, Alireza Ahmadianyazdi, Albert Folch
Article
Materials Science, Multidisciplinary
Jong Hyun Kim, Wahyu Martumpal Hamonangan, Shin-Hyun Kim
Summary: This research designs elastic photonic shells with enhanced color saturation and high deformability using W/O/W double-emulsion templates. The shells contain acrylate-based resin with non-close-packed arrays of silica particles, which are improved in crystalline order by increasing the concentration of water-soluble molecules. The coloration of the shells can also be tuned through osmotic inflation in hypotonic conditions.
ADVANCED OPTICAL MATERIALS
(2023)
Article
Chemistry, Physical
Sang-Mun Jung, Jinhyeon Lee, Jaesub Kwon, Byung-Jo Lee, Seung-Yeon Kang, Kyu-Su Kim, Sang-Hoon You, Young Jin Lim, Sung Gu Kang, Yong-Tae Kim
Summary: Thermo-electrochemical cells (TECs) are being studied as a viable option to harvest waste heat energy. In this study, a tungsten carbide (WCx) electrode was used as a substitute for expensive materials like Pt and nanostructured carbon. This non-noble-metal electrode significantly reduced the cost of the TEC system and delivered an impressive power output. The study demonstrates the potential of WCx as an economical and stable electrode material for waste heat energy harvesting.
ACS APPLIED ENERGY MATERIALS
(2023)
Article
Chemistry, Multidisciplinary
Jong Bin Kim, Hwan-Young Lee, Changju Chae, Su Yeon Lee, Shin-Hyun Kim
Summary: This study formulates high-performance Bingham inks by destabilizing silica particle suspensions, which swiftly transition from liquid to solid upon discharge, facilitating rapid, shrinkage-free printing. The resulting prints display structural colors and enhanced mechanical properties.
ADVANCED MATERIALS
(2023)
Article
Engineering, Environmental
Hyunbin Kim, Do Hyun Kim, Shin-Hyun Kim
Summary: Microreactors are crucial in nanoparticle synthesis, allowing for better control over reaction conditions and improving heat and mass transfer. However, traditional fabrication methods can be complex and expensive. The Bolt-nut microreactor offers a practical and cost-effective alternative, allowing for adjustable volume and easy cleaning, and achieving better size distribution and light output for quantum dots synthesis.
CHEMICAL ENGINEERING JOURNAL
(2023)
Article
Chemistry, Physical
Ye Hun Choi, Shin-Hyun Kim
Summary: A method for producing single-crystalline photonic supraballs is proposed by controlling the crystallization process through osmotic extraction in emulsion droplets. The method allows for a consistent rate of consolidation and improved selectivity of crystalline structures. By mixing particle-laden droplets and salt-dissolved droplets, the particle droplets shrink and crystallize while the salt droplets expand, resulting in the enrichment and crystallization of particles. The rate of enrichment is controlled by adjusting the salt concentration, enabling dominant production of single-crystalline structures in a relatively short consolidation time.
CHEMISTRY OF MATERIALS
(2023)
Article
Chemistry, Physical
Ji-Won Kim, Chao Chen, Hyunki Kim, Shin-Hyun Kim, Ryan C. Hayward
Summary: This study investigates the effect of surface tension on the light-induced wrinkling of hydrogel disks containing photothermally-active gold nanoparticles. By changing the surface tension through the concentration of a poly(vinyl alcohol) surfactant, a critical threshold for wrinkling is observed, followed by a decrease in wrinkle number with decreasing surface tension. Finite element simulations show similar trends as the experiments. The findings provide insights into controlling the interfacial behavior of reconfigurable and shape-morphing films.
Article
Chemistry, Multidisciplinary
Sehee Yang, Young Geon Kim, Sanghyuk Park, Shin-Hyun Kim
Summary: The researchers created photonic microcapsules with dual or triple stopbands, offering a wider range of colors through structural color mixing. They controlled the crystallization of colloidal mixtures using depletion forces and specific conditions, resulting in different particles and controlled ratios within the crystals.
ADVANCED MATERIALS
(2023)
Article
Chemistry, Multidisciplinary
Ye Hun Choi, Jiwoo Lee, Esther Amstad, Shin-Hyun Kim
Summary: This study explores the variation of surface arrangements in icosahedral clusters composed of colloids and identifies the determining factors behind the surface arrangement. The experimental approach of droplet-to-droplet osmotic extraction is used to efficiently assemble particles in emulsion droplets. The findings reveal that the sphericity of the clusters plays a pivotal role in determining the number of layers in the anti-Mackay shells on the surface.
Article
Chemistry, Multidisciplinary
Sanghyuk Park, Shin-Hyun Kim
Summary: This study presents a simple and efficient method for producing photonic micropatterns through bottom-up depletion-mediated regioselective growth of colloidal crystals. The method allows high-resolution micropatterning and control over the structural colors through concentration, depletant and salt, as well as particle size. Additionally, secondary colors can be generated through structural color mixing. The findings offer a general approach for designing elaborate photonic micropatterns suitable for various applications.
ADVANCED MATERIALS
(2023)
Article
Chemistry, Multidisciplinary
Hwan-Young Lee, Minbon Gu, Jeonghee Hwang, Hyerim Hwang, Young-Seok Kim, Su Yeon Lee, Shin-Hyun Kim
Summary: Auxetic photonic patterns are designed to provide ultra-sensitive mechanochromism. As the strains are locally amplified in the cut areas of the auxetic patterns, elastic photonic crystals in the cuts show significant color change even for small total strains. The sensitivity is as high as 60 nm/%, which is 20 times improved from bulk films, enabling intuitive colorimetric monitoring of strains.