期刊
JOURNAL OF COLLOID AND INTERFACE SCIENCE
卷 439, 期 -, 页码 69-75出版社
ACADEMIC PRESS INC ELSEVIER SCIENCE
DOI: 10.1016/j.jcis.2014.10.011
关键词
Nanowire; Polypyrrole; Aqueous rechargeable lithium batteries; Vanadium pentoxide
资金
- Natural Science Foundation of China [51201117, 51104121]
- Major State Basic Research Development Program (973 Program) [2012CB722701]
- Scientific Research Fund of Wuhan Textile University, Youth National Science Foundation of Shanxi Province [2013JQ6005]
- Scholarship Award for Excellent Doctoral Student granted by Ministry of Education of China [1343-71134001002]
Precursors of ammonium vanadium bronze (NH4V4O10) nanowires assembled on a conductive substrate were prepared by a hydrothermal method. After calcination at 360 degrees C, the NH4V4O10 precursor transformed to vanadium pentoxide (V2O5) nanowires, which presented a high initial capacity of 135.0 mA h g(-1) at a current density of 50 mA g(-1) in 5 M LiNO3 aqueous solution; while the specific capacity faded quickly over 50 cycles. By coating the surface of V2O5 nanowires with water-insoluble polypyrrole (PPy), the formed nanocomposite electrode exhibited a specific discharge capacity of 89.9 mA h g-1 at 50 mA g(-1) (after 100 cycles). A V2O5@PPy //LiMn2O4 rechargeable lithium battery exhibited an initial discharge capacity of 95.2 mA h g(-1); and after 100 cycles, a specific discharge capacity of 81.5 mA h g(-1) could retain at 100 mA g(-1). (C) 2014 Elsevier Inc. All rights reserved.
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