4.7 Article

Staudinger Vilarassa reaction: A powerful tool for surface modification and superhydrophobic properties

期刊

JOURNAL OF COLLOID AND INTERFACE SCIENCE
卷 457, 期 -, 页码 72-77

出版社

ACADEMIC PRESS INC ELSEVIER SCIENCE
DOI: 10.1016/j.jcis.2015.06.032

关键词

Superhydrophobic; Wetting properties; Nanostructures; Electropolymerization; Staudinger-Vilarrasa reaction

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Here we report for the time, the use of Staudinger-Vilarrasa reaction for fast surface functionalization. Using poly(3,4-ethylenedioxythiophene) nanofibrous surfaces bearing azido groups, this reaction allows for the functionalization of surfaces with amide linker in just 3 h. The functionalization by long alkyl chains induces the formation of highly hydrophobic surfaces while the surface structures are preserved. This reaction can be a key pathway for fast surface modification for a large range of applications such as in cell or bacterial adhesion, for example. (C) 2015 Elsevier Inc. All rights reserved.

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