Impact of the redox mediator sodium anthraquinone-2,6-disulphonate (AQDS) on the reductive decolourisation of the azo dye Reactive Red 2 (RR2) in one- and two-stage anaerobic systems

This work assessed the impact of the redox mediator sodium anthraquinone-2,6-disulphonate (AQDS) on the reductive decolourisation of the azo dye Reactive Red 2 (RR2) in one- and two-stage anaerobic systems (R-1 and R-2, respectively). The two-stage system achieved better colour removal efficiencies (52-62%) than the single-stage system (23-33%) in the absence of AQDS. Addition of AQDS accelerated the electrons transfer from the substrate (ethanol) to the dye, which increased the colour removal efficiency of both anaerobic systems (similar to 85%). Finally, the impact of acidogenic and methanogenic phases separation was masked by AQDS supplementation. (C) 2012 Elsevier Ltd. All rights reserved.