期刊
BIOMACROMOLECULES
卷 11, 期 9, 页码 2415-2421出版社
AMER CHEMICAL SOC
DOI: 10.1021/bm1005883
关键词
-
资金
- Conseil Regional de Champagne Ardenne and the Centre National de la Recherche Scientifique
- Conseil Regional Champagne Ardenne
- MENESR
- EU
The reactivity of various vinyl ethers and vinyloxy derivatives of ribose in the presence of diethyl fumarate or diethyl maleate was investigated for evaluating the potential of donor-acceptor-type copolymerization applied to unsaturated monomers derived from renewable feedstock. The photochemically induced polymerization of model monomer blends in the bulk state was monitored by infrared spectroscopy. The method allowed us to examine the influence of monomer pair structure on the kinetic profiles. The simultaneous consumption of both monomers was observed, supporting an alternating copolymerization mechanism. A lower reactivity of the blends containing maleates compared with fumarates was confirmed. The obtained kinetic data revealed a general correlation between the initial polymerization rate and the Hansen parameter OH associated with the H-bonding aptitude of the donor monomer.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据