Article
Polymer Science
Astrid Diekmann, Marvin C. V. Omelan, Ulrich Giese
Summary: Incorporating nanofillers into elastomers leads to composites with great potential, but concerns arise due to agglomeration of fillers. Different carbon nanotube pretreatment methods were analyzed to improve filler dispersion in polydimethylsiloxane (PDMS)/CNT composites. While solvent dispersion led to increased electrical conductivity, it also caused a softening effect due to solvent residues. Chemical functionalization improved compatibility but damaged CNTs, overshadowing the conductivity and reinforcement enhancement effects.
Article
Chemistry, Multidisciplinary
Gang Xiong, Zhanping Zhang, Yuhong Qi
Summary: Semiconductor photocatalytic materials have potential in antifouling applications due to their antibacterial properties, stability, and nontoxic nature. This study introduces g-C3N4/TNTs/CNTs (CNTC) photocatalytic composite powders into polydimethylsiloxane (PDMS) coatings to enhance their antifouling performance. The results show successful recombination of CNTC, which resulted in decreased recombination rate of photogenerated carriers. The addition of CNTC increased the hydrophobicity and roughness of the coatings while reducing the surface energy. CNTC effectively improved the anti-attachment performance of PDMS coatings to bacteria and benthic diatom.
Article
Energy & Fuels
Fatma Nur Tuzluca Yesilbag, Yasar Ozkan Yesilbag, Ahmad Huseyin, Ahmed Jalal Salih Salih, Mehmet Ertugrul
Summary: Optimizing interlayer spacing of 2D MXene is important for synthesizing 3D composite electrodes for energy storage. In this study, flexible and conductive MXene/BCN nanotube composite film electrodes were prepared, with a specific capacitance of 678 F g-1 and excellent cycle stability. The composite electrodes made of 2D MXene and 1D BCN nanotubes open up a new avenue for energy storage materials.
JOURNAL OF ENERGY STORAGE
(2023)
Article
Chemistry, Applied
Siyu Zhao, Xiheng Kang, Hanhan Fan, Chuanling Si, Xueping Song
Summary: The improvement of pseudo-capacitance is crucial for the performance of supercapacitors, with MnO2 being an ideal material for this purpose. A two-step method was used to load MnO2 onto ZAC, resulting in enhanced electrochemical performance. By sequentially loading alpha-MnO2, CNTs, and 8-MnO2 on ZAC, the composite material showed promising results in terms of capacitance retention and efficiency after 5000 cycles.
MICROPOROUS AND MESOPOROUS MATERIALS
(2022)
Article
Chemistry, Multidisciplinary
Giulia Massaglia, Marzia Quaglio
Summary: This paper introduces a novel method to synthesize a 3D composite aerogel, which shows high performance as an anode electrode in single chamber microbial fuel cells (SCMFCs). The electrode exhibits a high surface area, biocompatibility for bacterial proliferations, and improved electron pathways.
Article
Physics, Applied
Sergey Moseenkov, Igor Dorofeev, Kirill Dorozhkin, Natalya Sankova, Alexey Zavorin, Alexandra Serkova, Ekaterina Parkhomchuk, Valentin Suslyaev, Vladimir Kuznetsov
Summary: This study proposes a new method for producing polymer composites by adsorbing multiwalled carbon nanotubes on the surface of polystyrene spheres. The method allows control of cell size and conductivity of the composite. The study explores the effect of MWCNT concentration on the structure and electrophysical properties of the composites in a specific frequency range. The results show percolation behavior in the composite's conductivity and the formation of two subsystems of nanotubes on the PS surface, each influencing different frequency ranges.
JOURNAL OF APPLIED PHYSICS
(2022)
Article
Materials Science, Composites
Xixia Zhao, Xinyue Yu, Guijuan Wei, Fangong Kong, Wenhui Wang
Summary: A SnP3/CNTs composite electrode was successfully prepared through ball-milling technique and demonstrated excellent cyclic performance and rate capabilities for PIBs. The critical roles of CNTs matrix in buffering volume expansion, boosting electrical conductivity, and avoiding over thick SEI film were identified for the superior performances of the composite electrode. The results are expected to inspire the development of advanced tin phosphide based anode materials for PIBs.
COMPOSITES COMMUNICATIONS
(2021)
Article
Nanoscience & Nanotechnology
Shuiliang Wang, Zhequn Huang, Wenbo Shi, Dongwook Lee, Qixiang Wang, Wen Shang, Yosi Stein, Yang Shao-Horn, Tao Deng, Brian L. Wardle, Kehang Cui
Summary: This study demonstrates that amine-containing aromatic and cyclohexane molecules can effectively disperse single-walled carbon nanotubes (SWCNTs) in solvents, leading to stable dispersion at the single-tube level. The interaction between the amine group of the molecules and the pi bond of SWCNTs plays a crucial role in achieving excellent dispersibility and stability. Additionally, the enhanced thermal and electrical properties of SWCNT/epoxy nanocomposites through the introduction of these molecules provide a promising new approach for industrial applications.
ACS APPLIED MATERIALS & INTERFACES
(2021)
Article
Chemistry, Multidisciplinary
Marie N. Barshutina, Valentyn S. Volkov, Aleksey V. Arsenin, Dmitriy I. Yakubovsky, Alexander V. Melezhik, Alexander N. Blokhin, Alexey G. Tkachev, Alexander V. Lopachev, Vladislav A. Kondrashov
Summary: The paper presents a cost-effective and scalable approach to produce highly homogeneous graphene and CNT-based silicone composites with superior electrical and mechanical properties. The study investigates the influence of processing parameters, graphene/CNT ratio, and hybrid filler loading, finding optimal parameters for superior composite properties. The graphene/CNT hybrid system shows a synergistic effect that prevents aggregation and facilitates dispersion, contributing to the superior properties of the hybrid composites.
Article
Chemistry, Analytical
Fudan Zhu, Huilan Shi, Cunli Wang, Xian Zhou, Xin Zhang, Fengchun Yang
Summary: A disposable electrochemical sensor based on a bismuth selenide/carboxylic multiwalled carbon nanotube (Bi2Se3@MWNTs-COOH) nanocomposite has been designed for nitrite detection, showing excellent performance with fast electron transfer rate and high electrochemically active surface area. The sensor has a wide detection range of 0.01 mu M - 7.0 mM and a low detection limit of 0.002 mu M, making it an effective analytical tool for monitoring nitrite. This work provides new insights into nitrite detection and encourages exploration of rapid and cost-effective detection methods using nanocomposites and disposable systems.
SENSORS AND ACTUATORS B-CHEMICAL
(2021)
Article
Construction & Building Technology
Jiseul Park, Myungjun Jung, Yang-woo Lee, Hee-Young Hwang, Sung-gul Hong, Juhyuk Moon
Summary: Dispersion of carbon nanotubes (CNTs) is crucial for the performance of nanocomposites. However, the evaluation of CNT dispersion is limited. This study visualized the macroscopic distribution of CNTs in hardened cement matrix using confocal Raman microspectroscopy and optical microscope. The dispersion efficiency and heterogeneity were quantified to assess the dispersion quality. The experimental results highlight the importance of well-dispersed CNT suspension and suggest evaluating ultrasonication with superplasticizers for dispersion in cement composites.
CEMENT AND CONCRETE RESEARCH
(2023)
Article
Chemistry, Physical
Wenyu Liang, Igor Zhitomirsky
Summary: MXenes, such as Ti3C2Tx, are promising materials for supercapacitor electrodes. Colloidal techniques were used in the fabrication of Ti3C2Tx-Fe3O4-CNT electrodes with high areal capacitance. Celestine blue played a crucial role in improving the capacitive performance by serving as a co-dispersant for individual materials.
Article
Chemistry, Multidisciplinary
Fei Zhang, Danhui Ren, Lingqi Huang, Yinhang Zhang, Yuxuan Sun, Dan Liu, Qi Zhang, Wei Feng, Qingbin Zheng
Summary: Stretchable conductors with stable electrical conductivity under harsh mechanical deformations have been developed using 3D interconnected conductive graphite nanoplatelet welded carbon nanotube networks. The unique welding mechanism using GNPs enables high electrical conductivity, high stretchability, and long-term stability, allowing for applications in a myriad of new applications.
ADVANCED FUNCTIONAL MATERIALS
(2021)
Article
Chemistry, Inorganic & Nuclear
Hui Liu, Yuanke Wu, Pan Liu, Han Wang, Maowen Xu, Shu-juan Bao
Summary: A novel material with a nano-Co-armed carbon nanotube functional layer was proposed to enhance the stability of room temperature Na-S batteries by improving the adsorption and conversion efficiency of NaPSs, achieving high electronic conductivity and low decay rate. This unique structure delivered improved stable electrochemical performance with high coulombic efficiency and excellent capacity rate.
INORGANIC CHEMISTRY FRONTIERS
(2022)
Article
Engineering, Electrical & Electronic
Suraj Baloda, Navneet Gupta, Sumitra Singh
Summary: The pressure sensor based on multiwalled carbon nanotubes/polydimethylosiloxane composite has great potential in wearable healthcare devices and electronic-skins due to its high sensitivity, wide linear range, and biocompatibility.
IEEE TRANSACTIONS ON ELECTRON DEVICES
(2022)
Article
Engineering, Biomedical
Mehlika Karamanlioglu, Serap Yesilkir-Baydar
Summary: This study determined the influence and ideal ratios of different amounts of coconut oil in gelatin-based films as wound dressings. Increasing coconut oil content improved the mechanical properties, thermal stability, cell viability, and wound healing ability of the films. CO-2 and CO-4 showed the best performance among the samples.
JOURNAL OF BIOMATERIALS SCIENCE-POLYMER EDITION
(2024)
Article
Engineering, Biomedical
Yu-Min Chen, Chihoko Tokoda, Yasuhiko Tabata
Summary: The objective of this study is to establish strategies to uniformly proliferate cells in a three-dimensional nonwoven PET/EVOH scaffold by simple adjustments in seeding and culture methods and the scaffold design. The combination of dynamic and static seeding methods resulted in the highest seeding efficiency. Stirring culture allowed cells to proliferate to a greater extent, while opening holes in the scaffold improved cell distribution. Two 1-mm holes were found to be optimal for homogeneous cell proliferation. Different cell types showed similar behavior in the scaffold, indicating the applicability of the established procedure. The nonwoven PET/EVOH scaffold serves as a potential cell culture substrate for efficient cell proliferation.
JOURNAL OF BIOMATERIALS SCIENCE-POLYMER EDITION
(2024)
Article
Engineering, Biomedical
Majid Saeedi, Katayoun Morteza-Semnani, Jafar Akbari, Seyyed Mobin Rahimnia, Fatemeh Ahmadi, Hanieh Choubdari, Amir Lotfi, Seyyed Mohammad Hassan Hashemi
Summary: In this study, kojic acid loaded chitosan/collagen nanoparticles were produced using an ionic gelation and ultrasonic approach to enhance dermal delivery and anti-pigmentation effects. Increasing the amount of collagen in the nanoparticles led to larger particle size and higher entrapment efficiency of kojic acid. The nanoparticles were found to be spherical in shape and kojic acid was in an amorphous form. Skin permeability tests showed that the nanoparticles delivered more kojic acid to the dermal layers compared to plain gel. The nanoparticles were non-toxic and non-irritating, and exhibited stronger inhibition of melanin formation compared to free kojic acid. These findings suggest that the produced nanoparticles have potential as a nano-vehicle for dermal administration of kojic acid, providing new options for managing hyper-melanogenesis problems.
JOURNAL OF BIOMATERIALS SCIENCE-POLYMER EDITION
(2024)
Article
Engineering, Biomedical
Hue Thi Nguyen, Anh-Tuan Le, Thanh Thuy Nguyen, Tran Quang Huy, Thuy Thi Thu Nguyen
Summary: In this study, a chitosan and emodin formulation was prepared to enhance the solubility of emodin and exhibited synergic antibacterial activity against drug-resistant bacterial strains. The enhanced solubility of the formulation suggests its potential as a candidate for the treatment of infectious diseases caused by drug-resistant bacterial pathogens.
JOURNAL OF BIOMATERIALS SCIENCE-POLYMER EDITION
(2024)
Article
Engineering, Biomedical
Jiu Ge, Mengting Li, Jiahui Fan, Christian Celia, Yijun Xie, Qing Chang, Xiaoyong Deng
Summary: Bacterial infections pose a significant threat to human health, and the emergence of multidrug-resistant bacteria has reduced the effectiveness of antibacterial treatments. In this study, chitosan/silver nanoparticle complexes were developed to inhibit bacterial proliferation and induce membrane damage. The results demonstrated that increasing the chitosan concentration enhanced the antibacterial impact, and the nanoparticles showed broad-spectrum antimicrobial activity. The study provides valuable insights into the development of nano-antibacterial agents as a potential substitute for traditional antibiotics in medical applications.
JOURNAL OF BIOMATERIALS SCIENCE-POLYMER EDITION
(2024)