What factors influence the reactivity of C–H hydroxylation and C=C epoxidation by [FeIV(Lax)(1,4,8,11-tetramethyl-1,4,8,11-tetraazacyclotetradecane)(O)]n+

How Does Tunneling Contribute to Counterintuitive H-Abstraction Reactivity of Nonheme Fe(IV)O Oxidants with Alkanes?

(2015) Debasish Mandal et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ligand Field Effects and the High Spin–High Reactivity Correlation in the H Abstraction by Non-Heme Iron(IV)–Oxo Complexes: A DFT Frontier Orbital Perspective

(2015) Andranik Kazaryan et al.   ACS Catalysis

High-valent nonheme iron-oxo complexes: Synthesis, structure, and spectroscopy

(2012) Aidan R. McDonald et al.   COORDINATION CHEMISTRY REVIEWS

Tunnelling control of chemical reactions – the organic chemist's perspective

(2012) David Ley et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Evidence for a High-Spin Fe(IV) Species in the Catalytic Cycle of a Bacterial Phenylalanine Hydroxylase

(2011) Aram Joel Panay et al.   BIOCHEMISTRY

Methylhydroxycarbene: Tunneling Control of a Chemical Reaction

(2011) P. R. Schreiner et al.   SCIENCE

Substrate-Triggered Formation and Remarkable Stability of the C−H Bond-Cleaving Chloroferryl Intermediate in the Aliphatic Halogenase, SyrB2

(2009) Megan L. Matthews et al.   BIOCHEMISTRY

Theoretical study of cyclohexane hydroxylation by three possible isomers of [FeIV(O)(R-TPEN)]2+: does the pentadentate ligand wrapping around the metal center differently lead to the different stability and reactivity?

(2009) Yi Wang et al.   JOURNAL OF BIOLOGICAL INORGANIC CHEMISTRY

Steric hindrance effect of the equatorial ligand on Fe(IV)O and Ru(IV)O complexes: a density functional study

(2009) Yi Wang et al.   JOURNAL OF BIOLOGICAL INORGANIC CHEMISTRY

An Inverted and More Oxidizing Isomer of [FeIV(O)(tmc)(NCCH3)]2+

(2008) Kallol Ray et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Mononuclear non-heme iron enzymes with the 2-His-1-carboxylate facial triad: recent developments in enzymology and modeling studies

(2008) Pieter C. A. Bruijnincx et al.   CHEMICAL SOCIETY REVIEWS

A Two-State Reactivity Rationale for Counterintuitive Axial Ligand Effects on the CH Activation Reactivity of Nonheme FeIVO Oxidants

(2008) Hajime Hirao et al.   CHEMISTRY-A EUROPEAN JOURNAL

The Effect and Influence of cis-Ligands on the Electronic and Oxidizing Properties of Nonheme Oxoiron Biomimetics. A Density Functional Study

(2008) Sam P. de Visser et al.   JOURNAL OF PHYSICAL CHEMISTRY A

Axial Ligand Effects on the Geometric and Electronic Structures of Nonheme Oxoiron(IV) Complexes

(2008) Timothy A. Jackson et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Valence Bond Modeling of Trends in Hydrogen Abstraction Barriers and Transition States of Hydroxylation Reactions Catalyzed by Cytochrome P450 Enzymes

(2008) Sason Shaik et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY