期刊
BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY
卷 10, 期 -, 页码 969-974出版社
BEILSTEIN-INSTITUT
DOI: 10.3762/bjoc.10.95
关键词
enantioselective synthesis; hydroxy esters; scandium
资金
- National Natural Science Foundation of China [21102071]
- Fundamental Research Funds for the Central Universities [1107020522, 1082020502]
We show a convenient decarboxylative aldol process using a scandium catalyst and a PYBOX ligand to generate a series of highly functionalized chiral alpha-hydroxy esters. The protocol tolerates a broad range of beta-keto acids with inactivated aromatic and aliphatic alpha-keto esters. The possible mechanism is rationalized.
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