期刊
BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY
卷 10, 期 -, 页码 3122-3126出版社
BEILSTEIN-INSTITUT
DOI: 10.3762/bjoc.10.329
关键词
alkynylation; chiron approach; Ferrier-type C-glycosylation; macrolide
资金
- NIPER-Hyderabad
- CSIR, New Delhi as part of the XII Five Year Plan Programme under title ORIGIN [CSC-108]
- Ministry of Earth Science Programme, Drugs from the Sea [GAP-390]
- CSIR, New Delhi
An enantioselective formal total synthesis of aspergillide C is accomplished using commercially available tri-O-acetyl-D-galactal employing a Ferrier-type C-glycosylation, utilizing a Trost hydrosilylation and protodesilylation as key reactions.
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