☆ 4.5 Article

Air-stable, recyclable, and time-efficient diphenylphosphinite cellulose-supported palladium nanoparticles as a catalyst for Suzuki-Miyaura reactions

BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY (2011)

期刊

BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY

卷 7, 期 -, 页码 378-384

出版社

BEILSTEIN-INSTITUT

DOI: 10.3762/bjoc.7.48

关键词

diphenylphosphinite cellulose; heterogeneous catalysis; nanopalladium; polymer-supported catalyst; Suzuki-Miyaura reaction

类别

Chemistry, Organic

资金

National Natural Science Foundation of China [21072077, 20672046]
Guangdong Natural Science Foundation [10151063201000051, 8151063201000016]
Guangzhou Science & Technology Project [2010Y1-C511]

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摘要

A diphenylphosphinite cellulose palladium complex (Cell-OPPh2-Pd-0) was found to be a highly efficient heterogeneous catalyst for the Suzuki-Miyaura reaction. The products were obtained in good to excellent yield under mild reaction conditions. Moreover, the catalyst could be easily recovered by simple filtration and reused for at least 6 cycles without losing its activity.

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