期刊
BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY
卷 7, 期 -, 页码 735-739出版社
BEILSTEIN-INSTITUT
DOI: 10.3762/bjoc.7.83
关键词
flow chemistry; hydrogenation; polysilane; palladium; reduction
资金
- Japan Society for the Promotion of Science (JSPS)
- University of Tokyo, MEXT, Japan
- NEDO
- Global COE Program
- Grants-in-Aid for Scientific Research [21225002] Funding Source: KAKEN
Continuous flow systems for hydrogenation using polysilane-supported palladium/alumina (Pd/(PSi-Al(2)O(3))) hybrid catalysts were developed. Our original Pd/(PSi-Al(2)O(3)) catalysts were used successfully in these systems and the hydrogenation of unsaturated C-C bonds and a nitro group, deprotection of a carbobenzyloxy (Cbz) group, and a dehalogenation reaction proceeded smoothly. The catalyst retained high activity for at least 8 h under neat conditions.
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