期刊
BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY
卷 7, 期 -, 页码 1064-1069出版社
BEILSTEIN-INSTITUT
DOI: 10.3762/bjoc.7.122
关键词
homocoupling; iron salts; microreactor; organolithiums
资金
- Japan Society for the Promotion of Science
- NEDO
- Grants-in-Aid for Scientific Research [22750092, 21106002, 21106001] Funding Source: KAKEN
The use of FeCl3 resulted in a fast homocoupling of aryllithiums, and this enabled its integration with the halogen-lithium exchange reaction of aryl halides in a flow microreactor. This system allows the homocoupling of two aryl halides bearing electrophilic functional groups, such as CN and NO2, in under a minute.
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