期刊
AUSTRALIAN JOURNAL OF CHEMISTRY
卷 64, 期 2, 页码 153-159出版社
CSIRO PUBLISHING
DOI: 10.1071/CH10319
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资金
- EC [PITN-GA-2008-215399 - FINELUMEN]
- CNRS
- University of Strasbourg
- CNR [PM.P04.010]
- French Ministry of Research
- Institute of Advanced Studies of the University of Bologna
A stilbene derivative bearing a terminal alkyne unit has been prepared and grafted onto a T-h-symmetrical C-60 hexakis-adduct building block under alkyne/azide copper mediated Huisgen 1,3-dipolar cycloaddition conditions. The photophysical properties of the resulting fullerene derivative surrounded by 12 conjugated oligomers have been investigated. Upon excitation of the peripheral chromophores, an efficient intramolecular energy transfer to the C-60 core has been evidenced.
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